Reaction of electrochemically generated radical anions with phosphorylated ureas

Autor:	Z. Ya. Latypov, S. V. Lapshina, A. Gurylev, G. K. Budnikov, O. Yu. Kargina
Rok vydání:	1988
Předmět:	Nitrobenzene chemistry.chemical_compound Anthracene Reaction rate constant chemistry Hydrogen Benzophenone chemistry.chemical_element Molecule Protonation General Chemistry Photochemistry Chemical reaction
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 37:440-443
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00965350
Popis:	1. In the presence of phosphorylated ureas, oxygen, nitrobenzene, benzophenone, and anthracene are reduced in DMF on a mercury cathode according to the ECE mechanism, and the rate constants k2 and activation energies of the included chemical reaction were calculated. 2. Based on the kinetic data, the scheme of the process with included protonation of the radical anion in which any of the hydrogen atoms in the NH fragments of the PU molecules can participate was proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::461b7044e690b33d32fe2f73f94ec029 https://doi.org/10.1007/bf00965350 Zobrazit plný text záznamu Full text from SpringerLink