Free radical-induced C-allylation of α-bromolactones. Synthesis of 2-C-allyl-2-deoxy-d-arabino-and -d-ribono-1,4-lactones

Autor:	Roger Leger, Marco Alpegiani, Stephen Hanessian
Rok vydání:	1992
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Chemistry Stereochemistry Organic Chemistry Aldonic acid Halide Free-radical reaction General Medicine Biochemistry Vicinal Lactone Analytical Chemistry
Zdroj:	Carbohydrate Research. 228:145-155
ISSN:	0008-6215
Popis:	Application of the Keck C -allylation of organic halides to 2-bromo-2-deoxy- d -arabinolactone resulted in the formation of mixtures of 2- C -allyl lactones. The stereochemical preferences observed were dictated by the nature of vicinal and remotely placed substituents in the lactone.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::461977fc933f09d3183aa040a07272bc https://doi.org/10.1016/s0008-6215(00)90556-1 Zobrazit plný text záznamu