On the stability of the tetrahedral In-4VAgcomplex in silver halides

Autor:	M L Swanson, J C Austin
Rok vydání:	1995
Předmět:	Inorganic chemistry Halide Condensed Matter Physics Ion law.invention Silver chloride chemistry.chemical_compound Crystallography chemistry law Angular correlation Halogen Tetrahedron General Materials Science Spectroscopy Electron paramagnetic resonance
Zdroj:	Journal of Physics: Condensed Matter. 7:9747-9754
ISSN:	1361-648X 0953-8984
Popis:	A point defect complex in silver chloride consisting of a trivalent iron ion in a cube-centre interstitial site, tetrahedrally coordinated with four silver vacancies and four halogen ions, was previously detected by EPR. In this article we present evidence, obtained by perturbed angular correlation spectroscopy, for a similar defect complex for In3+ in AgCl and AgBr. We present data establishing the existence of this negatively-charged complex, describe its behaviour, and consider why a negatively-charged complex forms.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::461416f2685ad417a09d715094e0f006 https://doi.org/10.1088/0953-8984/7/50/009 Zobrazit plný text záznamu