Ru–BINAP-catalyzed asymmetric hydrogenation of keto esters in high pressure carbon dioxide

Autor: E. V. Starodubtseva, Maxim G. Vinogradov, V. A. Ferapontov, Sergei G. Zlotin, O. V. Turova, Nikolai S. Ikonnikov, Ilya V. Kuchurov
Rok vydání: 2012
Předmět:
Zdroj: Mendeleev Communications. 22:184-186
ISSN: 0959-9436
DOI: 10.1016/j.mencom.2012.06.003
Popis: Asymmetric hydrogenation of ethyl 4-chloro-3-oxobutyrate and dimethyl acetylsuccinate in high pressure CO 2 using [RuCl 2 (C 6 H 6 )] 2 –( R )-BINAP as the catalyst provides high ee values for the products.
Databáze: OpenAIRE