The reaction of carbanions with 2-substituted-2-nitropropanes

Autor:	Mikolaj Jawdosiuk, Glen A. Russell, Boguslaw Mudryk, Francisco Ros
Rok vydání:	1982
Předmět:	Alkane chemistry.chemical_classification Radical-nucleophilic aromatic substitution Radical substitution Chemistry Organic Chemistry Photochemistry Biochemistry Medicinal chemistry Ion Electron transfer Yield (chemistry) Drug Discovery Nitro Carbanion
Zdroj:	Tetrahedron. 38:1059-1067
ISSN:	0040-4020
DOI:	10.1016/0040-4020(82)80123-3
Popis:	The reaction of mono-enolate anions with O2NCMe2X where X = Cl, NO2, p-MePhSO2 yield coupling (RCOCH(R′)(CMe2NO2) and enolate dimerization products (RCOCH(R′)CH(R′)COR) by free radical chain mechanisms involving bimolecular substitution or electron transfer reactions between the enolate anion and the intermediate nitro alkane radical anion (XCMe2NO2− ).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4602d05fd5683de2d4ca29318c43c7c5 https://doi.org/10.1016/0040-4020(82)80123-3 Zobrazit plný text záznamu