Mutarotation of ?-D-arabinose in the presence of aliphatic-aromatic amino alcohols as catalysts

Autor: I. P. Murina, E. M. Cherkasova, V. A. Pavlov, E. I. Klabunovskii
Rok vydání: 1974
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 23:303-306
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf00924674
Popis: 1. The rate constants of the mutarotation ofβ-D-arabinose in 50% aqueous ethanol in the presence of the investigated catalysts obey the Bronsted function withβ = 0.84±0.01 at 20°. 2. The thermodynamic parameters of the activation of the mutarotation ofβ-D-arabinose under the action of the investigated catalysts are related by an isokinetic function (β = 250 ± 2K).
Databáze: OpenAIRE