Mutarotation of ?-D-arabinose in the presence of aliphatic-aromatic amino alcohols as catalysts
Autor: | I. P. Murina, E. M. Cherkasova, V. A. Pavlov, E. I. Klabunovskii |
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Rok vydání: | 1974 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 23:303-306 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00924674 |
Popis: | 1. The rate constants of the mutarotation ofβ-D-arabinose in 50% aqueous ethanol in the presence of the investigated catalysts obey the Bronsted function withβ = 0.84±0.01 at 20°. 2. The thermodynamic parameters of the activation of the mutarotation ofβ-D-arabinose under the action of the investigated catalysts are related by an isokinetic function (β = 250 ± 2K). |
Databáze: | OpenAIRE |
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