Sc, Ge co-doping NASICON boosts solid-state sodium ion batteries' performance
| Autor: | Tongen Lin, Ian R. Gentle, Ming Li, Masud Rana, Ruth Knibbe, Ardeshir Baktash, Meng Li, Yu Yin, Lianzhou Wang, Lingbing Ran, Baris Demir, Debra J. Searles |
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| Rok vydání: | 2021 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment Doping Analytical chemistry Energy Engineering and Power Technology 02 engineering and technology Electrolyte Conductivity 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Ion Phase (matter) Fast ion conductor General Materials Science Grain boundary 0210 nano-technology Monoclinic crystal system |
| Zdroj: | Energy Storage Materials. 40:282-291 |
| ISSN: | 2405-8297 |
| Popis: | Solid-state sodium ion batteries (SSSIBs) have been proposed to resolve the safety hazards of traditional liquid batteries. The sodium superionic conductor (NASICON), one of the most promising solid electrolyte candidates, has received much attention. However, the practical use of NASICON has been impeded by low ion mobility at room temperature (RT) and poor interfacial connectivity. Here, the improvement of both bulk and grain boundary conductivity has been achieved simultaneously via Sc and Ge co-doping. Bulk conductivity is increased by the Sc-doping, which increases the stability of the rhombohedral phase at RT, and the Ge-doping, which reduces the monoclinic to rhombohedral phase transformation temperature. The highest total conductivity of 4.64 × 10−3 S cm−1 was obtained for the Na3.125Zr1.75Sc0.125Ge0.125Si2PO12 structure. The improvement in conductivity due to the stabilisation of the rhombohedral phase was verified by DFT calculations. Finally, two different solid-state batteries using Na3V2(PO4)3 and Sn4P3@CNT as electrodes display impressive cycling capacities of 98 and 629 mAh g − 1 after 250 cycles, respectively. This co-doping principle also provides a framework to explore multiple-doping for other materials with similar structures. |
| Databáze: | OpenAIRE |
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