Versatile Solvothermal Synthetic Method and Structural Characterization of Lithium Coordination Networks
| Autor: | Zhi-Qiang Jiang, Yu-Feng Li, Jin Lu, Xue-Jun Zhu, Yu Du, Zai-Chun Huang, Yao Kang |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Materials science Polymers and Plastics chemistry.chemical_element Structural diversity 02 engineering and technology Polymer 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Characterization (materials science) Crystallography chemistry Materials Chemistry Lithium 0210 nano-technology |
| Zdroj: | Journal of Inorganic and Organometallic Polymers and Materials. 29:1447-1456 |
| ISSN: | 1574-1451 1574-1443 |
| Popis: | The reactions of LiOH·H2O with 1,3,5-benzenetricarboxylic acid (1,3,5-btc) under versatile solvothermal conditions produce a series of lithium coordination polymers, namely {[Li2(1,3,5-btc)(1,3,5-Hbtc)(DMF)](DMF)2}n (1), {[Li3(1,3,5-btc)(DMSO)3](H2O)}n (2), {((CH3)2NH)[Li2(1,3,5-btc)(H2O)]}n (3), {((CH3)2NH)[Li2(1,3,5-btc)(1,3,5-Hbtc)]}n (4), {((CH3)2NH)[Li2(1,3,5-btc)]}n (5) and [Li3(1,3,5-btc)(H2O)]n (6) (DMSO = dimethyl sulphoxide, DMF = N,N-dimethylformamide). Compound 1 and 4 exhibit two-dimensional framework, while compound 2, 3, 5 and 6 show three-dimensional network. The results demonstrate different solvents or different temperatures can generate the structural diversity. |
| Databáze: | OpenAIRE |
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