Intramolecular trapping of spiro radicals to produce unusual cyclization products from usual migration substrates

Autor: Jingming Zhang, Chengkou Liu, Yaqi Qiao, Minghui Wei, Wenjing Guan, Ziren Mao, Hong Qin, Zheng Fang, Kai Guo
Rok vydání: 2023
Předmět:
Zdroj: Chemical Science. 14:2461-2466
ISSN: 2041-6539
2041-6520
DOI: 10.1039/d2sc05768a
Popis: Unusual, highly complex and valuable spirocyclic compounds were produced through domino radical addition, intramolecular cyclization and ring opening instead of usual migration to the difunctionalization products of olefins.
Databáze: OpenAIRE