| Autor: |
Xiaobing Wan, Jiajun Liu, Hanghang Wang, Chunmei Liu, Yuanzheng Lv, Ying Shao, Xiaoguang Bao, Erbo Shi, Meishan Ji |
| Rok vydání: |
2016 |
| Předmět: |
|
| Zdroj: |
ChemInform. 47 |
| ISSN: |
0931-7597 |
| Popis: |
A novel strategy for the difunctionalization of styrenes was developed. This synthesis includes the use of electrophilic perfluoroalkyl and tert-butylperoxy radicals and produces (1-(tert-butylperoxy)-2-perfluoroalkyl)ethylbenzene at room temperature, which has been traditionally difficult to synthesize. With at least four radical species included in the transformation, its high chemoselectivity was extraordinary; the results were further elucidated using computational studies. The methodology also holds a good potential for application as a result of its mild reaction conditions, ease of further modification, and insensitivity to moisture and air. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
|
Plný text