Reactions on single-walled nanotubes: 2. Reactions on the nanosized surface of nanotubes in liquid hydrocyanic acid

Autor:	S. S. Bukalov, A. N. Krasnovskii, A. G. Ryabenko, O. M. Zhigalina, D. P. Kiryukhin, M. N. Larichev, Eugene N. Nikolaev, S. N. Sul’yanov, G. A. Kichigina
Rok vydání:	2014
Předmět:	chemistry.chemical_compound Ethanol chemistry Polymerization Reagent Radical Radiolysis Inorganic chemistry Physical and Theoretical Chemistry Photochemistry Chemical reaction
Zdroj:	High Energy Chemistry. 49:53-57
ISSN:	1608-3148 0018-1439
Popis:	Chemical reactions stimulated by γ-radiation in liquid hydrocyanic acid (HCN) in the presence of single-walled edcarbon nanotubes (SWCNTs) have been studied. The polymerization of HCN on the surface of nanotubes occurs several times more rapidly than in pure HCN, and the set of radiolysis products becomes poorer. It is likely that the approach of polymerizing reagents on the nanosized surface is limited by specific mutual orientations. Furthermore, the CN and H radicals add to the walls of the nanotubes and the nanotubes become soluble in water, ethanol, and acids.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4546491d57198a2018bb9d1ead02c1e0 https://doi.org/10.1134/s0018143915010130 Zobrazit plný text záznamu Full text from SpringerLink