Solubility Determination and Thermodynamic Models for 2-Methylnaphthalene in Different Solvents from T = (278.15 to 303.15) K

Autor:	Fang Zhang, Yaocun Tang, Guoji Liu, Li Xu, Long Wang
Rok vydání:	2015
Předmět:	Standard molar entropy Chemistry General Chemical Engineering Enthalpy Thermodynamics General Chemistry Thermodynamic databases for pure substances Molar solubility Gibbs free energy Enthalpy change of solution symbols.namesake symbols Physical chemistry Solubility Van 't Hoff equation
Zdroj:	Journal of Chemical & Engineering Data. 60:1699-1705
ISSN:	1520-5134 0021-9568
DOI:	10.1021/je5010627
Popis:	The solubility of 2-methylnaphthalene in different organic solvents was experimentally studied by the equilibrium method at temperatures from (278.15 to 303.15) K under atmospheric pressure. The solubility of 2-methylnaphthalene in all solvents increased with the increasing temperature. The solubility data were correlated with four thermodynamic models including the van’t Hoff equation, modified Apelblat equation, λh equation, and Wilson model. It was found that the calculated solubility with modified Apelblat equation provided a good agreement with the experimental values for the solubility behavior of 2-methylnaphthalene. The thermodynamic properties of the standard dissolution enthalpy, standard entropy, and the standard mole Gibbs free energy were evaluated based on the van’t Hoff analysis. The values of enthalpy of dissolution are positive, which indicate that the dissolution process of 2-methylnaphthalene in different organic solvents is endothermic.
Databáze:	OpenAIRE
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