A fully bio-based intumescent flame retardant for poly(butylene succinate)
| Autor: | Si Chen, Yu Chencheng, Xu Wang, Wu Feiyang, Yan Hu, Lin Shichao, Feng Zhu |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Phytic acid
Aqueous solution Composite number Guanosine Ionic bonding 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences Polybutylene succinate chemistry.chemical_compound chemistry General Materials Science 0210 nano-technology Intumescent Nuclear chemistry Fire retardant |
| Zdroj: | Materials Chemistry and Physics. 252:123222 |
| ISSN: | 0254-0584 |
| DOI: | 10.1016/j.matchemphys.2020.123222 |
| Popis: | A novel fully bio-based intumescent flame retardant PA-GU was prepared by green and convenient ionic reaction of phytic acid (PA) and guanosine (GU) in aqueous environment, being prepared by adding PA-GU completely derived from renewable feedstocks to poly(butylene succinate) (PBS). The tests results showed that when the addition amount of PA-GU was 10 wt%, the peak of heat release rate (pHRR) of the sample decreased 59.2% (from 1413 kW/m2 to 577 kW/m2), the total heat release (THR) decreased 38.6% (from 132 MJ/m2 to 81 MJ/m2), and the average mass loss rate decreased to 11 g/m2•s (from 13 g/m2•s) compared to PBS containing no additive, all of which gradually decreased with the increasement of PA-GU. The preparation of flame retardant PBS composite not only means the expansion of the application of PBS, but also provides a new idea for the preparation of completely biologically derived flame-retardant materials. |
| Databáze: | OpenAIRE |
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