Effective Methods of Preparation of Some Classes of Phosphororganic Compounds

Autor: S. A. Hovsepian, R. H. Khachatrian, S. V. Sayadian, M. H. Injikian, N. Yu. Grigorian
Rok vydání: 1990
Předmět:
Zdroj: Phosphorus, Sulfur, and Silicon and the Related Elements. 51:260-260
ISSN: 1563-5325
1042-6507
DOI: 10.1080/10426509008040794
Popis: The convenient methods of preparation of secondary and tertiary phosphines, phosphinoxides and phosphonates on the basis of corresponding P-H acids and alkyl-, allyl-, alle-nyl-, ethynylarylhalides, 1,3-diens, acetylenic and vinyl-acetylenic hydrocarbons as alkylating agents have been elaborated. The reactions were proceeded in organic solvents in the presence of potassium carbonate under the conditions of interphase catalysis in liquid-liquid, liquid-solid systems, as well as in superbasic medium (schemes 1, 2)
Databáze: OpenAIRE