A stochastic representation of the Coleman-Fox model for the description of sequences of stereochemical configurations

Autor: V. M. Rodin, V. A. Lovchikov
Rok vydání: 2014
Předmět:
Zdroj: Polymer Science Series B. 56:940-943
ISSN: 1555-6123
1560-0904
DOI: 10.1134/s156009041406013x
Popis: A model of the formation of sequences of stereochemical configurations in chain macromolecules that was proposed by Coleman and Fox is considered. Previously, it was thought that this model can not be represented by Markov statistics of any order. On the basis of an analysis of the model equations, it is shown that these sequences can be represented by Markov statistics and describe chain growth approximately with a precision similar to that of the classical second-order Markov model, widely used to describe stereosequences.
Databáze: OpenAIRE