Autor:	I. Yu. Bagryanskaya, A. G. Berdin, V. A. Raldugin, Yu. V. Gatilov, S. M. Adekenov, A. T. Kulyyasov, Tolstikov Genrikh A, Makhmut M. Shakirov, G. Habdolda, A. G. Druganov
Rok vydání:	2001
Předmět:	chemistry.chemical_classification chemistry.chemical_compound 13c nmr spectroscopy Rhaponticum serratuloides Chemistry Stereochemistry Molecule General Chemistry Spectroscopy Two-dimensional nuclear magnetic resonance spectroscopy Derivative (chemistry) Lactone
Zdroj:	Russian Chemical Bulletin. 50:537-542
ISSN:	1066-5285
Popis:	As part of our continuing studies of lactones from the aerial part of the plant Rhaponticum serratuloides, 15-O-deacetylrhaposerin and new guaianolide called rhaserin were isolated along with the well-known loliolide. The configuration of the C(17) asymmetric center in 15-O-deacetylrhaposerin was established by X-ray diffraction analysis. The molecular structure of rhaserin was determined based on the data from 1H and 13C NMR spectroscopy (including 2D NMR spectroscopy) of this lactone and its 4,15-O-isopropylidene derivative.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::44dac58734739329535d29231c91aff2 https://doi.org/10.1023/a:1011342130857 Zobrazit plný text záznamu Full text from SpringerLink