Rotationally resolved fluorescence as a probe of molecular photoionization dynamics

Autor:	Sandeep Kakar, Heung‐Cheun Choi, Erwin D. Poliakoff
Rok vydání:	1992
Předmět:	Range (particle radiation) Chemistry Photoionization mode General Physics and Astronomy Synchrotron radiation Rotational temperature Photoionization Physical and Theoretical Chemistry Atomic physics Photon energy Fluorescence Excitation
Zdroj:	The Journal of Chemical Physics. 97:6998-7001
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.463216
Popis:	We present rotationally resolved data for the v’=0 and v’=1 levels of N2+(B 2Σu+) produced via 2σu−1 photoionization of N2. The data are obtained over a broad photon energy range (19≤hνexc≤35 eV). This is made possible by using synchrotron radiation excitation in conjunction with dispersed fluorescence detection. The results exhibit both resonant and nonresonant effects.
Databáze:	OpenAIRE
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