Rotationally resolved fluorescence as a probe of molecular photoionization dynamics

Autor: Sandeep Kakar, Heung‐Cheun Choi, Erwin D. Poliakoff
Rok vydání: 1992
Předmět:
Zdroj: The Journal of Chemical Physics. 97:6998-7001
ISSN: 1089-7690
0021-9606
Popis: We present rotationally resolved data for the v’=0 and v’=1 levels of N2+(B 2Σu+) produced via 2σu−1 photoionization of N2. The data are obtained over a broad photon energy range (19≤hνexc≤35 eV). This is made possible by using synchrotron radiation excitation in conjunction with dispersed fluorescence detection. The results exhibit both resonant and nonresonant effects.
Databáze: OpenAIRE