Steric and electronic effects on the chemistry of molybdenum octahedrally co-ordinated by six nitrogen atoms. The molecular structure of [Mo{HB(3,5-Me2C3N2H)3}(NO)(pyrollide)2]

Autor:	Bryan D. Neaves, Anthony J. Edwards, Jon A. McCleverty, Chris Jones, Najat Al Obaidi, Katherine P. Brown, Susan A. Hollins
Rok vydání:	1984
Předmět:	Steric effects Stereochemistry chemistry.chemical_element Crystal structure Pyrazole chemistry.chemical_compound Crystallography chemistry Molybdenum Pyridine Electronic effect Molecular Medicine Imidazole Tetrahydrofuran
Zdroj:	Journal of the Chemical Society, Chemical Communications. :690
ISSN:	0022-4936
DOI:	10.1039/c39840000690
Popis:	[Mo{HB(3,5-Me2C3N2H)3}(No)I2] reacts with the nitrogen heterocycles Z to give [Mo{HB(3,5-Me2C3N2H)3}(NO)Z2]+, where Z = pyridine, imidazole, N-methylimidazole, or pyrazole, with monosidium organoamides to give [Mo{HB(3,5-Me2C3N2H)3}(NO)Y2] where Y = NHEt–, NHPh–, p-NHC6H4Me–, or pyrollide, and with moist tetrahydrofuran to give [Mo{HB(3,5-Me2C3N2H)3}(NO)I{O[CH2]4I}]; the molecular structure of [Mo{HB(3, 5-Me2C3N2H)3}(NO)-(pyrollide)2] has been determined.
Databáze:	OpenAIRE
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