Beckmann's mixture versus Beckmann reaction
| Autor: | Nicholas Paolella, Galantay Eugene E, Clarence Hoffman |
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| Rok vydání: | 1970 |
| Předmět: | |
| Zdroj: | Journal of the Chemical Society D: Chemical Communications. :274 |
| ISSN: | 0577-6171 |
| DOI: | 10.1039/c29700000274 |
| Popis: | An apparently general, hitherto unobserved reaction pathway for α-oximino-ketones, mechanistically related to the Semmler–Wolff aromatization, is described and put in the framework of “non-Beckmannian reactions”; a novel explanation is suggested for the formation, in Ac2O–AcOH–HCl, of anomalous Beckmann rearrangement products. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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