Synthesis of Oligo-enynes Using [Fe(alkene)(CO)n] Scaffolds. Z/E-Selective Wittig- and Horner-type Olefination Reactions of η-Carbonyl Groups in η4-Diene and γ-Carbonyl Groups in η2-Alkene Complexes of Iron

Autor:	Rainer Schobert, Jutta Böhmer
Rok vydání:	1998
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Diene chemistry Alkene Stereochemistry Wittig reaction General Chemistry Medicinal chemistry
Zdroj:	Journal of Chemical Research. :372-373
ISSN:	1364-5560 0308-2342
Popis:	β-Oxo-dienetricarbonyliron complexes 4 and γ-oxo-alkenecarbene complexes 5 undergo olefinations with a wide range of phosphonates and phosphoranes with high E- or Z-selectivity and give the free oligo-en(yn)es or carbamates, respectively, upon oxidative demetalation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::443d5bdaa992d4f97c84d2ad846eacd2 https://doi.org/10.1039/a801240g Zobrazit plný text záznamu