Enhancement of blue holographic properties in Zr4+-doped near stoichiometric Fe:LiNbO3 crystals
| Autor: | Yexia Fan, Chao Xu, Zemin Yu, Kuo Fu, Wenhui Li |
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| Rok vydání: | 2012 |
| Předmět: |
Materials science
Absorption spectroscopy business.industry Doping Analytical chemistry Photorefractive effect Atomic and Molecular Physics and Optics Electronic Optical and Magnetic Materials Crystal Optics Absorption edge Atomic ratio Electrical and Electronic Engineering business Saturation (magnetic) Stoichiometry |
| Zdroj: | Optics & Laser Technology. 44:362-365 |
| ISSN: | 0030-3992 |
| DOI: | 10.1016/j.optlastec.2011.07.015 |
| Popis: | The near stoichiometric LiNbO 3 crystals co-doped with ZrO 2 and Fe 2 O 3 have been grown from a Li-rich melt (Li/Nb=1.38, atomic ratio) by the Czochralski method in air atmosphere at the first time. The OH − absorption and UV–vis absorption spectra were characterized to investigate the defect structure of the crystals. The appearances of the 3479 cm −1 absorption peak and 358 nm absorption edge manifest that the composition of the grown crystal is close to the stoichiometric ratio. The blue holographic properties were also measured by the two-wave coupling experiments. As a result, in the near stoichiometric Zr:Fe:LiNbO 3 crystals, photorefractive response speed, recording sensitivity, and two-wave coupling gain coefficient are significantly enhanced. Meanwhile, the high saturation diffraction efficiency is still maintained. These findings prove that the material of near stoichiometric Zr:Fe:LiNbO 3 crystals are a promising candidate for blue photorefractive holographic recording. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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