Covalent triazine framework-supported palladium nanoparticles for catalytic hydrogenation of N-heterocycles
| Autor: | Ping Chen, Lin Liu, Guotao Wu, Teng He |
|---|---|
| Rok vydání: | 2015 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment Magnesium Inorganic chemistry chemistry.chemical_element General Chemistry Nitrogen Catalysis Metal chemistry.chemical_compound chemistry Covalent bond visual_art Polymer chemistry medicine visual_art.visual_art_medium General Materials Science Dehydrogenation Activated carbon medicine.drug Triazine |
| Zdroj: | Journal of Materials Chemistry A. 3:16235-16241 |
| ISSN: | 2050-7496 2050-7488 |
| Popis: | A covalent triazine framework (CTF) with high surface area, large amount of nitrogen functionalities, and high porosity and basicity was employed as a support for palladium nanoparticles (NPs). A well-dispersed Pd/CTF-1 catalyst with uniform distribution of Pd particles was successfully synthesized in the present study. The as-prepared 4% Pd/CTF-1 catalyst showed a markedly improved activity in the hydrogenation of N-heterocyclic compounds compared to the activated carbon (AC)-supported catalyst, i.e., the Pd/CTF-1 catalyst exhibits ca. 3.6 times faster reaction than Pd/AC in the hydrogenation of N-methylpyrrole. Characterization of Pd/CTF indicated electron donation from the N in CTF to the metallic Pd NPs, showing intensified electronic interaction between the Pd NPs and CTF support, which is responsible for the enhanced activities for the catalytic hydrogenation of N-heterocycles. |
| Databáze: | OpenAIRE |
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