Colloid and Nanosized Catalysts in Organic Synthesis: XXI. Reduction of Nitroarenes Catalyzed by Immobilized Nickel Nanoparticles
| Autor: | V. M. Mokhov, D. N. Nebykov, K. V. Shcherbakova, E. V. Nishchik, Yu. L. Zotov, Yu. V. Popov |
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| Rok vydání: | 2019 |
| Předmět: |
010405 organic chemistry
Magnesium Inorganic chemistry chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Chemical reaction 0104 chemical sciences Catalysis Nitrobenzene Nickel chemistry.chemical_compound Aniline Adsorption chemistry medicine Activated carbon medicine.drug |
| Zdroj: | Russian Journal of General Chemistry. 89:1549-1553 |
| ISSN: | 1608-3350 1070-3632 |
| Popis: | It has been found that nickel nanoparticles on NaX zeolite, γ-alumina, activated carbon, or magnesium oxide support catalyze the reduction of nitrobenzene and its homologs affording aniline and its derivatives in high yield. The effect of the substrate on the process in a continuous reactor at atmospheric hydrogen pressure has been investigated. The use of activated carbon or magnesium oxide as a carrier allows proceeding of the reaction at 80–100°C. |
| Databáze: | OpenAIRE |
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