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Ph2SiH2 [775-12-2] C12H12Si (MW 184.33) InChI = 1S/C12H12Si/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10H,13H2 InChIKey = VDCSGNNYCFPWFK-UHFFFAOYSA-N CsF [13400-13-0] CsF (MW 151.91) InChI = 1S/Cs.FH/h;1H/q+1;/p-1 InChIKey = XJHCXCQVJFPJIK-UHFFFAOYSA-M (reagent for the reduction of aldehydes,1, 2 ketones,1, 2 and esters;3 selective 1,2-reduction of enones2, 4 and enals2, 4) Physical Data: Ph2SiH2: bp 95–97 °C; d 0.993 g cm−3. CsF: mp 683 °C. Solubility: Ph2SiH2: sol THF. CsF: sol H2O; slightly sol THF, MeCN. Form Supplied in: Ph2SiH2: clear liquid; widely available. CsF: white solid; widely available. Drying: anhydrous CsF is prepared by flame drying under vacuum, taking care not to fuse the salt. Handling, Storage, and Precautions: Ph2SiH2 should be used in a fume hood. |
