ChemInform Abstract: Dideoxygenation on the 3′,4′-Positions of an α-Linked Disaccharide Derivative: A Key Intermediate for New Aminoglycoside Synthesis

Autor:	Hiroyoshi Kuzuhara, Nobuo Sakairi, Mitsuo Hayashida
Rok vydání:	1990
Předmět:	chemistry.chemical_compound chemistry Stereochemistry Aminoglycoside Disaccharide General Medicine Maltose Catalytic hydrogenation Derivative (chemistry)
Zdroj:	ChemInform. 21
ISSN:	0931-7597
Popis:	A 2′,6′-diamino-1,6-anhydro disaccharide derivative (6) was prepared from maltose. The 3′,4′-diol system of 6 was successfully converted into the 3′-ene system by application of the Corey–Winter procedure, giving the hex-3′-enopyranose derivative (8). Catalytic hydrogenation of 8 gave the dideoxy derivative, a key intermediate for the synthesis of a new aminoglycoside.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::43ccfd36a5ee6a9a571305eb3f9e0312 https://doi.org/10.1002/chin.199039304 Zobrazit plný text záznamu Plný text