Copper(I) and gold(I) thiolate precursors to bimetallic nanoparticles
| Autor: | Jill E. Millstone, Banghao Chen, Chau M. Tran, William Shepard, Mohsan Khan, Erik Elkaim, Robert J. Papoular, Lauren E. Marbella, Milan Gembicky, A. Timothy Royappa |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Aqueous solution Nanoparticle chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Copper 0104 chemical sciences Amorphous solid Inorganic Chemistry chemistry Covalent bond Polymer chemistry Materials Chemistry Thiol Side chain Physical and Theoretical Chemistry 0210 nano-technology Bimetallic strip |
| Zdroj: | Polyhedron. 155:359-365 |
| ISSN: | 0277-5387 |
| DOI: | 10.1016/j.poly.2018.08.068 |
| Popis: | Copper(I) and gold(I) thiolates were synthesized in quantitative or near-quantitative yield by the direct reaction of aqueous Cu(NO3)2 or HAuCl4 with aqueous thiols HSCH2CH2OH and HSCH2CH2OCH2CH2OH. The resulting highly insoluble thiolates had spectroscopic and bulk characteristics consistent with the formation of coordination polymers of general formula [M(SR)]n. The gold(I) thiolates were found to be amorphous solids with significant aurophilic interactions. The copper(I) thiolates, however, formed crystalline solids without discernible cuprophilic interactions. Characterization of the solid state structure of these latter thiolates showed that they consisted of covalently linked ca. two-atom thick Cu–S layers separated by layers of hydrogen bonded thiol side chains. |
| Databáze: | OpenAIRE |
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