The asymmetric hetero-Diels–Alder reaction and addition of allylic organometallics to 10-N,N-dicyclohexylsulphamoyl-(2R)-isobornyl glyoxylate

Autor:	Janusz Jurczak, Anna Czapla, Zofia Urbańczyk-Lipkowska, Katarzyna Kiegiel, Tomasz Bauer, Artur Chajewski, Zbigniew Wielogorski
Rok vydání:	1999
Předmět:	Inorganic Chemistry Addition reaction Allylic rearrangement Stereochemistry Chemistry Organic Chemistry Rigid structure Glyoxylate cycle Physical and Theoretical Chemistry Catalysis Diels–Alder reaction
Zdroj:	Tetrahedron: Asymmetry. 10:2101-2111
ISSN:	0957-4166
DOI:	10.1016/s0957-4166(99)00212-8
Popis:	The recent development of very effective chiral auxiliaries has led to the design of 10- N , N -dicyclohexylsulphamoyl-( R )-isoborneol, which is similar to Oppolzer's (2 R )-bornane-10,2-sultam but less effective on account of a less rigid structure. 10- N , N -Dicyclohexylsulphamoyl-( R )-isobornyl glyoxylate was examined in Diels–Alder and organometallic addition reactions. The results obtained were compared with those achieved by application of N -glyoxyloyl-(2 R )-bornane-10,2-sultam.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::439f7abfa37f143e0d7e540f6c0f8531 https://doi.org/10.1016/s0957-4166(99)00212-8 Zobrazit plný text záznamu Full Text from ScienceDirect