One-pot multicomponent synthesis of N-sulfonyl amidines using magnetic separable nanoparticles-decorated N-heterocyclic carbene complex with copper
| Autor: | Audumbar Patil, Suresh S. Patil, Arvind Pawar, Shivanand Gajare, Gajanan Rashinkar, Rajanikant Kurane |
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| Rok vydání: | 2021 |
| Předmět: |
Sulfonyl
chemistry.chemical_classification Thermogravimetric analysis Benzimidazole Materials science 010405 organic chemistry chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Copper 0104 chemical sciences Tosyl azide chemistry.chemical_compound chemistry Phenylacetylene Polymer chemistry Ionic liquid Carbene |
| Zdroj: | Research on Chemical Intermediates. 47:2801-2820 |
| ISSN: | 1568-5675 0922-6168 |
| Popis: | Magnetic separable nanoparticles-decorated N-heterocyclic carbene complex with copper (MNP[1-Methyl benzimidazole]NHC@Cu) has been prepared by covalent grafting of ionic liquid like 1-methyl benzimidazole unit on the surface of chlorofunctionalized Fe3O4 magnetic nanoparticles (MNPs) followed by metallation with copper(I) iodide. MNP[1-Methyl benzimidazole]NHC@Cu complex has been characterized by different techniques including Fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), energy-dispersive X-ray (EDX) analysis, X-ray diffraction (XRD), transmission electron microscopy (TEM) and vibrating sample magnetometer (VSM). MNP[1-Methyl benzimidazole]NHC@Cu complex was successfully implemented as heterogeneous catalyst in one-pot multicomponent synthesis of N-sulfonyl amidines from phenylacetylene, tosyl azide and amines at room temperature. Complex could be recycled six times without significant loss in the yield of product. |
| Databáze: | OpenAIRE |
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