Synthesis, crystal structure and reactivities of the first η4-vinylketenimine metal complexes

Autor:	Kazumi Nakatsu, Yoshinobu Takaegami, Take-aki Mitsudo, Yoshihisa Watanabe, Hiroyoshi Watanabe, Yoshiki Miyagawa, Yukiatsu Komiya, Kenji Kinoshita
Rok vydání:	1980
Předmět:	Diffraction Chemistry Organic Chemistry Crystal structure Methylation Biochemistry Inorganic Chemistry Metal visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Molecule Organic chemistry Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 190:C39-C42
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)85920-3
Popis:	The first examples of η4-vinylketenimine metal complex (IV) were prepared by the reaction of (η3-vinylcarbene)tricarbonyliron with isonitriles. The molecular structure of IV was determined by an X-ray diffraction study. Methylation of IV gave novel η4-vinylketeniminium metal complexes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4372b7b0b59ca439c84bbf2c04727fe8 https://doi.org/10.1016/s0022-328x(00)85920-3 Zobrazit plný text záznamu