Further measurements of the rotational spectrum of COF2: Improved molecular constants for the ground and ν2 states
| Autor: | W. Lewis-Bevan, Edward A. Cohen |
|---|---|
| Rok vydání: | 1991 |
| Předmět: |
chemistry.chemical_classification
Physics Infrared Far-infrared laser Rotational transition State (functional analysis) Atomic and Molecular Physics and Optics Nuclear magnetic resonance chemistry Rotational spectrum Rotational spectroscopy Physical and Theoretical Chemistry Atomic physics Ground state Inorganic compound Spectroscopy |
| Zdroj: | Journal of Molecular Spectroscopy. 148:378-384 |
| ISSN: | 0022-2852 |
| DOI: | 10.1016/0022-2852(91)90394-p |
| Popis: | Additional measurements of the rotational spectrum of COF2 in the 200–600 GHz region have led to improved rotational parameters for the ground vibrational state. These parameters have been used in refitting the ν2 infrared spectrum near 963 cm−1. Results using both Ir A and IIIr S Watson reduced Hamiltonians are presented. The new upper state parameters reproduce recently measured FIR laser frequencies with an RMS of 0.25 MHz. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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