The Effect of Water on the Heterogeneously Catalyzed Selective Oxidation of Acrolein: An Isotope Study

Autor:	Alfons Drochner, Herbert Vogel, Nina Blickhan, Tina Petzold
Rok vydání:	2014
Předmět:	Organic Chemistry Inorganic chemistry Acrolein chemistry.chemical_element Photochemistry Heterogeneous catalysis Oxygen Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Carbon dioxide Mixed oxide Physical and Theoretical Chemistry Acrylic acid Carbon monoxide
Zdroj:	ChemCatChem. 6:2053-2058
ISSN:	1867-3880
Popis:	The effect of water on the selective gas phase oxidation of acrolein to acrylic acid on a Mo/V/W mixed oxide catalyst was studied by performing steady-state isotopic transient kinetic analysis experiments with H218O. Experiments were performed in the temperature range of 90–345 °C at ambient pressure. It could be shown that acrolein exchanges its carbonylic oxygen with oxygen from water even at low temperatures ( 200 °C), the oxygen atoms of the water molecules incorporate into all oxidation products such as acrylic acid, carbon monoxide, and carbon dioxide.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4342dbf677406e9426836d06ea556754 https://doi.org/10.1002/cctc.201400099 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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