Low Thermal Expansion Modulated by Off-Stoichiometric Effect in Nonstoichiometric Laves Phase Hf0.87Ta0.13Fe2+x Compounds
Autor: | Wenhai Song, Wei Tong, Tong Peng, W.B. Jiang, Xuebin Zhu, Jianchao Lin, Yanwei Ding, Longfu Li, Yuping Sun, Xuekai Zhang, Cheng Yang, He Lin, Feng Zhu |
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Rok vydání: | 2019 |
Předmět: |
010405 organic chemistry
business.industry Chemistry Analytical chemistry Laves phase 010402 general chemistry 01 natural sciences Thermal expansion 0104 chemical sciences law.invention Inorganic Chemistry Ferromagnetism Negative thermal expansion law Phase (matter) Microelectronics Physical and Theoretical Chemistry business Electron paramagnetic resonance Stoichiometry |
Zdroj: | Inorganic Chemistry. 58:16818-16822 |
ISSN: | 1520-510X 0020-1669 |
Popis: | Materials with a low coefficient of thermal expansion (CTE) are extremely demanded in many fields, varying from microelectronics to space technology. Here we report a novel method to achieve low CTE, which differs essentially from the conventional way that uses additives with negative thermal expansion (NTE) to compensate for the positive CTE of the matrix. The stoichiometric Hf0.87Ta0.13Fe2+x (x = 0) shows a giant NTE, which is gradually suppressed with increasing x and finally changed to near-zero thermal expansion (ZTE) at x ≈ 0.4. The excess Fe was suggested to form anti-site defects by occupying the 4f sites. As revealed by electron spin resonance (ESR) spectra, the weakened NTE is closely related to a slower ferromagnetic (FM) ordering process than observed at x = 0. In addition, the CTE can be further tuned by introducing an extra α-Fe phase to achieve a low CTE (e.g., 3.3 ppm/K for x = 1.0) with markedly enhanced mechanical properties, beneficial to applications. |
Databáze: | OpenAIRE |
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