ChemInform Abstract: Stereoselective Synthesis of F-Alkyl α,β-Unsaturated Esters and Their Epoxidation

Autor:	M. Lanier, R. Pastor, M. Haddach, Jean G. Riess
Rok vydání:	2010
Předmět:	chemistry.chemical_classification chemistry Electrophile Amphiphile Stereoselectivity General Medicine Medicinal chemistry Alkyl
Zdroj:	ChemInform. 24
ISSN:	0931-7597
DOI:	10.1002/chin.199336163
Popis:	Strong electrophilic Z and E 3- F -alkyl 2-propenoates have been prepared stereoselectively. Their extremely difficult epoxidation has been achieved with retention of stereohemistry using t-BuO 2 Li, leading to F -alkyl glycidic esters, which are useful building blocks for the synthesis of new amphiphiles.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::43161f283904a3fbd4ea85ba27ebf3ed https://doi.org/10.1002/chin.199336163 Zobrazit plný text záznamu Plný text