Optimization of Catalytic Cocracking of Vacuum Distillate and Bio-Oxygenates in the Presence of Zeolite ZSM-5 Using Two-Factor Regression Analysis
| Autor: | S. N. Khadzhiev, K. I. Dementiev, T. A. Palankoev |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
010405 organic chemistry
Chemistry General Chemical Engineering Energy Engineering and Power Technology General Chemistry Raw material 010402 general chemistry complex mixtures 01 natural sciences 0104 chemical sciences law.invention Catalysis chemistry.chemical_compound Fuel Technology Chemical engineering Geochemistry and Petrology law Yield (chemistry) Acetone ZSM-5 Zeolite Distillation Oxygenate |
| Zdroj: | Petroleum Chemistry. 59:675-681 |
| ISSN: | 1555-6239 0965-5441 |
| DOI: | 10.1134/s0965544119070119 |
| Popis: | The features of the catalytic conversion of acetone and glycerol in a mixture with a hydrotreated vacuum distillate in the presence of zeolite catalysts containing Y and ZSM-5 have been studied. It has been shown that in the presence of zeolite Y, the highest yield of total C2–C4 olefins (24.1%) is achieved in the case of the conversion of the petroleum feedstock with an acetone-rich additive. The introduction of a catalytic additive based on ZSM-5 can significantly increase the yield of light olefins in the cracking of glycerol-rich feedstock. A synergistic effect in the transformation of a mixture of acetone and glycerol under these conditions has been observed, which is manifested in a decrease in the yield of C2–C4 olefins and an increase in the yield of gasoline fraction components. A significant influence of oxygenated feedstock additives on the intensity of hydrogen transfer reactions catalyzed by a combination of zeolites Y and ZSM-5 has been revealed. |
| Databáze: | OpenAIRE |
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