Tris(1-cyclopropyl-6-methyl-2-(N-methylaminocarbonyl)-4-oxo-1,4-dihydropyridin-4-olato)iron(III) dimethylformamide sesquisolvate dihydrate

Autor:	Regis Leung-Toung, Yingsheng Wang, Michael Spino, Tim Fat Tam, Alan J. Lough
Rok vydání:	2005
Předmět:	Tris chemistry.chemical_compound Denticity Chemistry Stereochemistry Hydrogen bond Dimethyl formamide General Materials Science General Chemistry Crystal structure Condensed Matter Physics Medicinal chemistry Ion
Zdroj:	Acta Crystallographica Section E Structure Reports Online. 61:m2601-m2603
ISSN:	1600-5368
Popis:	In the crystal structure of the title compound, [Fe(C11H13N2O3)3]·1.5C3H7NO·2H2O, the FeIII ion is six-coordinated in a distorted octa­hedral configuration consisting of six donor O atoms from three bidentate ligands. The Fe complex crystallizes with two mol­ecules of water and one and a half mol­ecules of dimethyl­formamide (DMF). The three amino­carb­oxy groups (CONHCH3) are all rotated out of the planes of their respective pyridinone rings. Inter­molecular O—H⋯O and N—H⋯O hydrogen bonds contribute to the stabilization of the crystal structure.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::42da83c856fd16769b32ffc33139349c https://doi.org/10.1107/s1600536805036251 Zobrazit plný text záznamu Plný text ve formátu PDF