Exo-Selective and Enantioselective Photoenolization/Diels–Alder Reaction

Autor:	Haibing He, Shuanhu Gao, Baochao Yang, Mengmeng Xu, Min Hou
Rok vydání:	2021
Předmět:	Chemistry Ligand Stereochemistry Organic Chemistry Enantioselective synthesis Physical and Theoretical Chemistry Biochemistry Diels–Alder reaction
Zdroj:	Organic Letters. 23:7487-7491
ISSN:	1523-7052 1523-7060
DOI:	10.1021/acs.orglett.1c02719
Popis:	An unusual exo-selective photoenolization/Diels-Alder reaction of electron-rich 2-methylbenzaldehydes and dienophiles containing a benzoyl group at its α position was reported herein. The chiral TADDOL-type ligand plays a key role in this process: (1) accelerating the reaction; (2) controlling the enantioselectivity; and (3) improving and tuning the diastereoselectivity of the reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::42d56b0f41d0029518659941815b018c https://doi.org/10.1021/acs.orglett.1c02719 Zobrazit plný text záznamu