High-Yield Synthesis of PPh3-Ligated Decanuclear Tl–Pd Cluster, Pd9[Tl(acac)](CO)9(PPh3)6: Comparative Analysis of Tl(I)–Pd(0) Bonding Connectivities with Known Tl–Pd Clusters and Resulting Insight Concerning Their Dissimilar Dynamic Solution Behavior

Autor:	Charles G. Fry, Nicky Vo, Lawrence F. Dahl, Evgueni G. Mednikov
Rok vydání:	2012
Předmět:	Inorganic Chemistry Crystallography Chemistry Yield (chemistry) Organic Chemistry Cluster (physics) Physical and Theoretical Chemistry
Zdroj:	Organometallics. 31:2878-2886
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om201150x
Popis:	The new Tl(I)–Pd(0) cluster Pd9[μ3/3-Tl(acac)](μ2-CO)6(μ3-CO)3(PPh3)6 (1) was prepared in high yields (over 90%), both by reaction of Pd10(CO)12(PPh3)6 (4), PPh3, and TlPF6 in THF in the presence o...
Databáze:	OpenAIRE
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