In quest of strong neutral organic bases and superbases—supramolecular systems containing four pyridine subunits

Autor:	Zvonimir B. Maksić, Ines Despotović, Borislav Kovačević
Rok vydání:	2007
Předmět:	inorganic chemicals Organic base Hydrogen bond Chemistry Organic Chemistry Supramolecular chemistry Cationic polymerization Resonance (chemistry) Biochemistry Combinatorial chemistry chemistry.chemical_compound Drug Discovery Pyridine Organic chemistry Acetonitrile Conjugate
Zdroj:	Tetrahedron Letters. 48:261-264
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2006.11.046
Popis:	It is shown by a reliable DFT method that supramolecular structures 1 and 2, constructed using pyridine as an essential building block, act as powerful neutral organic superbases in the gas phase and in acetonitrile due to cationic resonance and hydrogen bonding in the conjugate acids amplified by the NMe2 groups placed at strategic positions on the molecular backbone.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::427e76593a5cdad16df22945cba697c0 https://doi.org/10.1016/j.tetlet.2006.11.046 Zobrazit plný text záznamu Full Text from ScienceDirect