Pressure-Raman study of resonant TO(Γ)–two-phonon decay processes in ZnS: Comparison of three isotope compositions

Autor:	R. E. Tallman, Manuel Cardona, Núria Garro, T. M. Ritter, Jorge Serrano, B. A. Weinstein, R. Lauck, Andrés Cantarero
Rok vydání:	2004
Předmět:	Isotope Stable isotope ratio Chemistry Phonon Analytical chemistry Atmospheric temperature range Condensed Matter Physics Molecular physics Spectral line Electronic Optical and Magnetic Materials symbols.namesake Kinetic isotope effect symbols Density of states Raman spectroscopy
Zdroj:	physica status solidi (b). 241:3143-3148
ISSN:	1521-3951 0370-1972
DOI:	10.1002/pssb.200405221
Popis:	Pressure-Raman studies (to 15 GPa, at 300 K and 16 K) are reported on 64 Zn 34 S, 68 Zn 32 S, and natural ZnS to compare the effects of resonant 3-phonon mixing on the TO(Γ) phonons for the different isotope compositions. Under pressure the TO(F) Raman profiles exhibit several distinct features, and a sharp Lorentzian TO(Γ) peak eventually emerges at a threshold pressure P Th that differs for each isotope composition. These effects are due to resonant mixing of the TO(Γ) phonon with TA + LA combination modes. Calculations based on a bond-charge model and perturbation theory reproduce the observed pressure variations in the shape and the width of the TO(r) peaks. It is shown that these changes relate to singularities in the TA + LA density of states. Mass scaling of the TO(Γ) and TA + LA modes explains the isotope effect on F Th , and leads to the estimate γ LA(W) ∼1.2.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::427e11e9d230c4b71d39ee9bd1ed191e https://doi.org/10.1002/pssb.200405221 Zobrazit plný text záznamu Plný text