X-ray Crystal Structure of the N-(2-hydroxy-1-naphthalidene)phenylglycine Schiff Base. Synthesis and Characterization of its Transition Metal Complexes

Autor:	Munirathinam Nethaji, Rashmi V. Shenoy, Manjula S. Patil, Kalagouda B. Gudasi, Ramesh S. Vadavi, Siddappa A. Patil
Rok vydání:	2006
Předmět:	Schiff base Ligand Inorganic chemistry Metals and Alloys chemistry.chemical_element Zinc Crystal structure Inorganic Chemistry chemistry.chemical_compound Crystallography Deprotonation chemistry Transition metal Materials Chemistry Cobalt Organometallic chemistry
Zdroj:	Transition Metal Chemistry. 31:580-585
ISSN:	1572-901X 0340-4285
Popis:	The design and synthesis of the new amino acid Schiff base, N-(2-hydroxy-1-naphthalidene)phenylglycine (Hhnpg) has been described along with the single crystal X-ray crystallographic studies. Copper(II), nickel(II), cobalt(II), manganese(II) and zinc(II) complexes of Hhnpg were synthesized for the first time, and were characterized on the basis of elemental analysis, conductivity measurements, spectral (i.r., 1H-n.m.r., u.v.–vis., e.p.r.), magnetic and thermal studies. The i.r. spectral studies of all the complexes exhibit a similar feature about the ligating nature of the ligand to the metal ions and reveal that the ligand has coordinated through the carbonyl oxygen, azomethine nitrogen and deprotonated hydroxyl oxygen. The conductance data of the complexes suggest them to be non-electrolytes. The microbial activity of the ligand and the complexes was investigated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::423f3e9548044d12ab0f814a9e585e57 https://doi.org/10.1007/s11243-006-0031-3 Zobrazit plný text záznamu Full text from SpringerLink