Biomaterial Functionalized Graphene-Magnetite Nanocomposite: A Novel Approach for Simultaneous Removal of Anionic Dyes and Heavy-Metal Ions

Autor: Sujoy K. Das, Priyadarshani Choudhary, Thanusu Parandhaman, Baskaran Ramalingam
Rok vydání: 2018
Předmět:
Zdroj: ACS Sustainable Chemistry & Engineering. 6:6328-6341
ISSN: 2168-0485
Popis: Despite of immense application potential of graphene in wastewater treatment, the colloidal stability, aggregation and recyclability remains a major challenge. To address this issue, we report biomaterial functionalized graphene-magnetite (Bio-GM) nanocomposite as a novel recyclable material for treatment of wastewater containing dyes and heavy metals. The integration of biomaterial including living cells of Shewanella oneidensis with graphene-magnetite nanocomposite was characterized through UV–vis, FTIR, FESEM and fluorescent microscopic studies. The contact angle measurement depicted the hydrophilic property (water contact-angle 27.93°), whereas VSM result demonstrated super paramagnetic behavior of the nanocomposite with saturation magnetization value of 30.2 emu/g. The Bio-GM nanocomposite exhibited excellent adsorption capacity toward dyes and Cr6+ in both single and multicomponent system with removal capacity of 189.63 ± 7.11 and 222.2 ± 8.64 mg/g of dyes and Cr6+, respectively, suggesting selectiv...
Databáze: OpenAIRE