Excess Volumes of Ethyl Acetate + Toluene, + o-Chlorotoluene, and + p-Chlorotoluene from 283.15 to 303.15 K

Autor:	Ioanna E. Molinou, Maria M. Palaiologou
Rok vydání:	1995
Předmět:	chemistry.chemical_compound Molar volume P-chlorotoluene Volume (thermodynamics) Chemistry General Chemical Engineering O-chlorotoluene Ethyl acetate Analytical chemistry Organic chemistry General Chemistry Toluene
Zdroj:	Journal of Chemical & Engineering Data. 40:880-882
ISSN:	1520-5134 0021-9568
DOI:	10.1021/je00020a031
Popis:	Excess volumes (V E ) of binary mixtures of ethyl acetate with toluene and its o- and p-chloro derivatives have been determined from density measurements from 283.15 to 303.15 K over the entire composition range. Excess volumes are negative for all mixtures at all temperatures. The VE values are close to zero for the ethyl acetate + toluene system. The values decrease in the order toluene, o-chlorotoluene, and p-chlorotoluene. The effect of temperature on the excess volume is (∂V E /∂T) p , being generally negative.
Databáze:	OpenAIRE
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