Modelling of magneto-chiral enantioselective photochemistry

Autor: Geert L. J. A. Rikken, Cyrille Train, B. Malézieux, E. Raupach
Rok vydání: 2000
Předmět:
Zdroj: Chemical Physics. 261:373-380
ISSN: 0301-0104
DOI: 10.1016/s0301-0104(00)00284-6
Popis: We present a kinetic model to describe the recently observed magneto-chiral enantioselective photochemistry when irradiating with unpolarized light and applying a static magnetic field. The model shows that both true and cascaded magneto-chiral enantioselective photochemistry occur and yields expressions for their respective magnitudes. Comparison of the predictions of our model with the experimental results shows good agreement.
Databáze: OpenAIRE