SYNTHESIS N-PHENYLAMINEDITHIOCARBAMATE AS CHELATING AGENT IN SOLVENT EXTRACTION

Autor: Husein H. Bahti, Soja Siti Fatimah, Vera Musfiroh, Zackiyah Zackiyah, Iwan Hastiawan, Anna Permanasari
Rok vydání: 2014
Předmět:
Zdroj: Chimica et Natura Acta. 2
ISSN: 2541-2574
2355-0864
DOI: 10.24198/cna.v2.n3.9160
Popis: Dithiocarbamate derivatives is a versatile ligand that contain two atoms of sulfur as a strong electrondonor. It combines with metals. N-phenylaminedithiocarbamate has synthesized and applied in solvent exctration. Synthesis carried out with addition carbon disulphide to N-phenylamine and concentrated pottasium hydroxyde in metanol. The result was characterized by spectroscopy 1H-NMR, 13C-NMR, FTIR, Elemental Analysis, that showed molecular structure was significant. Applied N-Phenylaminedithiocarbamate in solvent extraction showed precent of result Cu(II), Co(II), Cr(III) and Ni (II) were 90.45% - 99.99% at pH 4-9.
Databáze: OpenAIRE