ADSORPTION FROM LIQUID MIXTURES AT SOLID SURFACES*

Autor:	J. J. Kipling, C. G. Gasser
Rok vydání:	1960
Předmět:	chemistry.chemical_compound Adsorption Chemistry Inorganic chemistry Monolayer General Engineering Mixing (process engineering) Oxide Molecule Physical and Theoretical Chemistry Absorption (chemistry) Benzene Chemical reaction
Zdroj:	The Journal of Physical Chemistry. 64:710-715
ISSN:	1541-5740 0022-3654
DOI:	10.1021/j100835a002
Popis:	There are at least four major factors which appear to be important in considering adsorption from tbe liquid phase onto solids: (a) the thickness of the adsorbed film, (b) the orientation of the adsorbed molecules, (c) the the liquid components. These factors probably are relevant in the choice of solutes designed to stabilize dispersions. Adsorptton by charcoal from mixtures of benzene with each of the lower aliphatic alcohols is considered in the light of these four factors. Adsorption can be interpreted as being confined to a monolayer, the alcohol molecules being adsorbed with the major axis parallel to the solid surface. The competitive adsorption is affected both by interaction between the liquid components and by strong interaction between the alcohol molecules and oxide complexes on the adsorbing surface. (auth)
Databáze:	OpenAIRE
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