Mixed Metal Thiophosphate Fe2–xCoxP2S6: Role of Structural Evolution and Anisotropy
| Autor: | Muhammad Arslan Shehzad, Mercouri G. Kanatzidis, Roberto dos Reis, Vinayak P. Dravid, Yea-Shine Lee, Daniel G. Chica, Matthew Cheng, Abishek K. Iyer, Eric K. Qian |
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| Rok vydání: | 2021 |
| Předmět: | |
| Zdroj: | Inorganic Chemistry. 60:17268-17275 |
| ISSN: | 1520-510X 0020-1669 |
| Popis: | Metal chalcophosphates, M2P2Q6 (M = transition metals; Q = chalcogen), are notable among the van der Waals materials family for their potential magnetic ordering that can be tuned with an appropriate choice of the metal or chalcogen. However, there has not been a systematic investigation of the basic structural evolution in these systems with alloying of the crystal subunits due to the challenge in the diffusion process of mixing different metal cations in the octahedral sites of M2P2Q6 materials. In this work, the P2S5 flux method was used to enable the synthesis of a multilayered mixed metal thiophosphate Fe2-xCoxP2S6 (x = 0, 0.25, 1, 1.75, and 2) system. Here, we studied the structural, vibrational, and electronic fingerprints of this mixed M2P2Q6 system. Structural and elemental analyses indicate a homogeneous stoichiometry averaged through the sample over multiple layers of Fe2-xCoxP2S6 compounds. It was observed that there is a correlation between the intensity of specific phonon modes and the alloying concentration. The increasing Co alloying concentration shows direct relations to the in-plane [P2S6]4- and out-of-plane P-P dimer vibrations. Interestingly, an unusual nonlinear electronic structure dependence on the metal alloying ratio is found and confirmed by two distinct work functions within the Fe2-xCoxP2S6 system. We believe this work provides a fundamental structural framework for mixed metal thiophosphate systems, which may assist in future studies on electronic and magnetic applications of this emerging class of binary cation materials. |
| Databáze: | OpenAIRE |
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