31P13C shift correlated 2D NMR spectra of the AA'X spin system: Determination of PP coupling constants and their relative signs in symmetrical diphosphonates

Autor:	Gisela Ohms, Gisbert Grossmann, Haiko Beckmann
Rok vydání:	1992
Předmět:	Coupling constant Nuclear magnetic resonance Chemistry Spin system Strong coupling Diphosphonates Physical chemistry General Materials Science Product operator formalism General Chemistry Nuclear magnetic resonance spectroscopy Two-dimensional nuclear magnetic resonance spectroscopy Spectral line
Zdroj:	Magnetic Resonance in Chemistry. 30:860-864
ISSN:	1097-458X 0749-1581
DOI:	10.1002/mrc.1260300912
Popis:	The indirect determination of P-P coupling constants and their relative signs in some symmetrical diphosphonates by 31 P- 13 C 2D NMR is introduced. Advantages and disadvantages of this method and others for the determination of the coupling constants of chemically equivalent nuclei are discussed. Strong coupling effects are analysed by means of simulated 2D spectra and the product operator formalism
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::41cfe2f7c3b70401a542b4427580476c https://doi.org/10.1002/mrc.1260300912 Zobrazit plný text záznamu Plný text