Photoelectron spectrum of the vinyl radical: downward revision of the C2H3-ionization potential
Autor: | Peter Chen, Joel A. Blush |
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Rok vydání: | 1992 |
Předmět: | |
Zdroj: | The Journal of Physical Chemistry. 96:4138-4140 |
ISSN: | 1541-5740 0022-3654 |
Popis: | We report the vacuum-UV photoelectron spectrum of the vinyl radial, C 2 H 3 , in a supersonic molecular beam. We find IP[C 23 ]=8.25 +0.20 -0.05 eV. Our ionization potential, which is lower than other reported values, combined with ΔH o BDE,O [C 2 H 3 -H]=105-110 kcal/mol |
Databáze: | OpenAIRE |
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