Photoelectron spectrum of the vinyl radical: downward revision of the C2H3-ionization potential

Autor:	Peter Chen, Joel A. Blush
Rok vydání:	1992
Předmět:	Photoemission spectroscopy Chemistry General Engineering Physical chemistry Supersonic speed Physical and Theoretical Chemistry Ionization energy Molecular beam
Zdroj:	The Journal of Physical Chemistry. 96:4138-4140
ISSN:	1541-5740 0022-3654
Popis:	We report the vacuum-UV photoelectron spectrum of the vinyl radial, C 2 H 3 , in a supersonic molecular beam. We find IP[C 23 ]=8.25 +0.20 -0.05 eV. Our ionization potential, which is lower than other reported values, combined with ΔH o BDE,O [C 2 H 3 -H]=105-110 kcal/mol
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::41cd999548d1849c5e794f1c5f79a151 https://doi.org/10.1021/j100190a004 Zobrazit plný text záznamu