Dihydrogen reduction of nitroaromatics, alkenes, alkynes using Pd(II) complexes both in normal and high pressure conditions

Autor:	Priyanka Sagar, P.K. Santra
Rok vydání:	2003
Předmět:	chemistry.chemical_classification Ligand Process Chemistry and Technology Kinetics Nitro compound Homogeneous catalysis Rate equation Photochemistry Catalysis chemistry.chemical_compound chemistry Yield (chemistry) Anthranilic acid Physical and Theoretical Chemistry
Zdroj:	Journal of Molecular Catalysis A: Chemical. 197:37-50
ISSN:	1381-1169
DOI:	10.1016/s1381-1169(02)00600-3
Popis:	Pd(II) complexes of S-Triazines and anthranilic acid were found very efficient towards the catalytic hydrogenation of organic nitrocompounds, alkenes, alkynes, etc. No diminished catalytic activity was observed even after 6–8 repeated catalytic runs. Profound effect on the rate of reduction and nature of yield were observed in presence of extra ligand. Kinetics were studied. Mechanism has been proposed and rate equation has been derived.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::41bdd829ff985843158b83ad46fcafa6 https://doi.org/10.1016/s1381-1169(02)00600-3 Zobrazit plný text záznamu Full Text from ScienceDirect