Far‐Infrared Spectra of Mercuric Halides and Their Dioxane Complexes

Autor:	R. J. Jakobsen, Y. Mikawa, J. W. Brasch
Rok vydání:	1966
Předmět:	Far infrared Chemistry High pressure Solid-state Analytical chemistry General Physics and Astronomy Halide Physical chemistry chemistry.chemical_element Physical and Theoretical Chemistry Spectral line Mercury (element)
Zdroj:	The Journal of Chemical Physics. 45:4528-4535
ISSN:	1089-7690 0021-9606
Popis:	The far‐infrared spectra (600–60 cm−1) of HgCl2, HgBr2, HgI2 (red), and their one‐to‐one p‐dioxane complexes (in the solid state) were investigated. All of the observed spectra, except those of HgI2, were assigned on the base of the symmetry properties of the crystals. High‐pressure effects were investigated for the anti‐symmetric stretching vibration of HgCl2 and its dioxane complex. The frequency shifts of all of the compounds in the various states, from the gaseous state through the dioxane complex under high pressure, were elucidated in terms of the distance between the mercury atom and its nearest neighbors.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::418be159da7812964f2a6b5c815cd8cd https://doi.org/10.1063/1.1727533 Zobrazit plný text záznamu